Sediment record of heavy metals over the last 150 years in Northeast China: implications for regional anthropogenic activities.

Evidence from terrestrial sedimentary heavy metals record is a robust indicator of anthropogenic activity changes. Heavy metals and particle sizes in 210Pb-dated sediment cores extracted from Hulun and Chagan lakes were measured to reconstruct the sediment record and evaluated health risk of heavy metals in the last 150 years in Northeast China. In general, the particle size of Hulun Lake was finer with more contents of clay than Chagan Lake, while the concentrations of most heavy metals in Hulun Lake was lower. Prior to the 1970s, significant positive correlations between most heavy metals and clay, indicating that that they were likely co-transported and both lakes were dominated by natural inputs. The two records showed significant increases in concentrations of heavy metals between 1970s and 1990s, which were associated with recent anthropogenic activities derived from principal component analysis of clay and heavy metals. Specifically, the exploitation of mineral resources and traffic source in the Hulun Lake, and the emissions of pesticides and fertilizers from agricultural activity, and the combustions of coal and fossil fuels from industrial activity in the Chagan Lake. Since 1990s, natural processes was the main source of heavy metals in Hulun Lake due to the environmental protection policy, while emissions of industrial, agricultural and domestic sewage were still the main source in Chagan Lake. Overall carcinogenic risks caused by single heavy metal elements determined for the two lakes were considered to be acceptable. However, Cr was associated with a risk for children across since 1970s which should be paid more attention.

Occurrence, sources and potential risks of polycyclic aromatic hydrocarbons in a permafrost soil core, northeast China.

Polycyclic aromatic hydrocarbons (PAHs) in an AMS 14C-dated permafrost soil core extracted from continuous permafrost zone were measured to reconstruct the pollution history from the early Holocene (ca. 15480 a BP) and its potential risks under climate changes were evaluated in northeast China. Total PAH concentrations varied from 209 to 2161 ng/g through the core, which were moderately contaminated in the surface but heavily contaminated historically. Factor analysis indicated that volcanic activity, diagenesis from biological precursors and palaeo forest fires were dominant PAH sources, while petroleum emission was identified in the active layer due to the construction of China-Russia oil pipeline. Significant increases in 5-ring, 6-ring and 7 carcinogenic PAHs (p < 0.05) were observed from surface to the interface of the active layer and ice-rich permafrost layer, showing a selective downward migration in the active layer which might be effected by the repetitive cycles of freezing and thawing. Results implied that PAHs in the ice-rich permafrost layer could lead to an unpredictably serious consequence under the further climate warming.